刘化章，现任浙江工业大学教授、博士生导师、工业催化研究所所长；工业催化博士点和博士后科研流动站首席科学家、浙江省多相催化重点实验室主任、浙江省工业催化重点学科带头人；美国科学发展协会AAAS会员。兼任中国化工学会理事兼化肥专业委员会名誉主任委员、中国化学会催化专业委员会委员、《Chinese Journal of Chemical Engineering》、《石油化工设备》、《工业催化》等杂志编委。
刘化章教授从事工业催化剂及化工工艺技术工作50年。在化肥催化剂研究中，对Fe3O4、Fe1-xO两代熔铁催化剂和第二代钌催化剂都做出重大改进。突破自20世纪初熔铁催化剂发明以来催化剂组成为磁铁矿时具有最高活性的经典结论，发明了新一代Fe1-xO基催化剂体系，这是氨合成催化剂研究的重大突破，是我国独创的一项原创性高技术成果，并建立了以单相理论为核心的我国原创的Fe1-xO催化剂理论体系。发表论文340余篇。研究成果被选编入10余本高等学校教材和专著中。开发成功A110-2、A301、ZA-5等系列新型氨合成催化剂，在实验技术、催化剂制造技术、催化反应器、成形技术、催化反应工程以及合成系统模拟与优化计算等各个方面做出系统的创新，建立了自成体系的工程技术系统。先后获得国家发明二等奖、国家发明三等奖、国家科技进步二等奖各1项，化工部和浙江省科技进步一等奖6项，中国专利发明创造金奖及国际金奖多项，中国、美国、英国、德国和丹麦等国发明专利23项。先后获国家杰出专业技术人才、国家有突出贡献的中青年科技专家、全国有突出贡献的留学回国人员、全国五一劳动奖章、《侯德榜化工科学技术奖》成就奖和浙江省科技进步重大贡献奖、浙江省特级专家、浙江省功勋教师等荣誉称号。
目錄：
Preface
Foreword
Chapter 1.Historical Evolution of Catalysts for Ammonia Synthesis
1.1 Introduction of Catalysts for Ammonia Synthesis
1.1.1 Co-Mo hydrogenation catalysts
1.1.2 Zinc oxide desulfurizer
1.1.3 Hydrocarbon steam reforming catalysts
1.1.4 CO high-temperature shift catalysts
1.1.5 CO low-temperature shift catalysts
1.1.6 Methanation catalysts
1.1.7 Refine catalysts
1.2 Historical Retrospect of Catalysts for Ammonia Synthesis
1.2.1 Basic studies on physical chemistry of ammonia synthesis reaction
1.2.2 Realization of ammonia synthesis under high pressure
1.2.3 Development of fused iron catalysts for ammonia synthesis
1.2.4 Development of ammonia synthesis catalysts in China
1.2.5 Development trend of ammonia synthesis catalysts
1.3 Development of Magnetite Fe304 Based Fused Iron Catalysts
1.3.1 Magnetite Fe304 based fused iron catalysts
1.3.2 Development of Fe304 based catalysts containing cobalt
1.4 Discovery of Wiistite Based Fused Iron Catalysts
1.4.1 Search for new breakthrough of the technique
1.4.2 Activity of wiistite Fe1-xO based catalysts
1.4.3 Reduction of Fe1-xO based catalysts
1.4.4 Technical characteristics of wiistite-based catalysts
1.4.5 Significance of the Fe1-xO-based catalysts in theory
1.4.6 Industrial application
1.5 Discovery of Ruthenium Based Catalysts
1.5.1 Properties of the elements in the activation of dinitrogen
1.5.2 Properties of the elements in ammonia synthesis
1.5.3 Alloying effect
1.5.4 Activated carbon supported ruthenium catalysts for ammonia synthesis
References
Chapter 2.Catalytic Reaction Mechanisms of Ammonia Synthesis
2.1 Introduction
2.1.1 The development of catalysis theory
2.1.2 The chemical essences of catalysis
2.1.3 The methodology of catalytic investigation
2.2 Adsorption and Heterogeneous Catalysis
2.2.1 Adsorption and heterogeneous catalysis
2.2.2 Non-uniformity of the surface of heterogeneous catalysts
2.2.3 Isotherms of chemisorptions
2.2.4 Rate of adsorption: Elovich equation
2.2.5 Chemisorption state
2.2.5.1 Chemisorption states of hydrogen
2.2.5.2 Adsorption states of nitrogen
2.2.5.3 Infrared spectroscopy study of nitrogen adsorption
2.2.5.4 The study of electronic energy spectroscopy for nitrogen adsorption
2.2.5.5 The study of adsorption of N2 on non-iron metals
2.3 Mechanism of Catalytic Ammonia Synthesis Reaction
2.3.1 Elementary reactions
2.3.2 Catalytic reaction mechanisms for ammonia synthesis
2.3.2.1 The mechanisms of ammonia synthesis reaction
2.3.2.2 The mechanisms of ammonia decomposition
2.3.2.3 Isotope exchanges of N2
2.3.2.4 Distinguishing reaction mechanisms
2.3.3 Analysis of microreaction intrinsic kinetics of ammonia synthesis
2.3.3.1 Analysis of reactor
2.3.3.2 The conclusion of microkinetic analysis
2.4 Kinetics of Overall Reactions for Ammonia Synthesis
2.4.1 General relation between overall reaction and elementary steps
2.4.2 Two-step sequences
2.4.3 Fundamental hypothesis of Temkin theory
2.4.4 The reaction rate equation of Temkin-Pyzhev for ammonia synthesis
……
Chapter 3.Chemical Composition and Structure of FusedIron Catalysts
Chapter 4.Preparation of Fused Iron Catalysts
Chapter 5.Reduction of Fused Iron Catalysts
Chapter 6.Ruthenium Based Ammonia Synthesis Catalysts
Chapter 7.Performance Evaluation and Characterization of Catalysts
Chapter 8.Performance and Application of Catalysts
Chapter 9.Effect of Catalyst Performance on the Economic Benefits of Catalytic Process
Chapter 10.Innovation and Speculation
Index
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